Kufotokozera
Lithium sulfide Li2S 3n4n(99.9%, 99.99%) ndi kristalo woyera wachikasu, CAS 12136-58-2, MW 45.95, kachulukidwe 1.66g/cm3, malo osungunuka 938 ° C, kuwira kwa 1372 ° C, amachitira mwamphamvu ndi madzi ndi sungunuka m'madzi, Mowa ndi asidi koma osasungunuka mu alkali.Lithium Sulfide ilipo mu mitundu iwiri ya orthorhombic ndi cubic structure yokhala ndi kachulukidwe ka 1.75g/cm.3ndi 1.63g/cm3motsatira.Kukhala anti-fluorite compound semiconductor ndi cubic Li2S an indirect band-gap semiconductor ya 3.865 eV,Lithium sulfidendiopangidwa mwapadera kuti agwiritse ntchito mabatire apamwamba pomwe atha kugwiritsidwa ntchito ngati zinthu za electrode kapena ngati kalambulabwalo wa ma electrolyte olimba.Poyerekeza ndi organic madzi kapena gel electrolyte, olimba electrolyte Lithium Sulfide ali ndi ubwino mkulu chitetezo, bata matenthedwe ndi electrochemical bata, lalikulu lithiamu ion conductivity ndi otetezeka mu osiyanasiyana voteji.
Mapulogalamu
Lithium sulfide Li2S ndi Li2S+GeS2+ P2S5 ndi Li2S+SiS2+ Al2S3 amaonedwa ngati zingamuthandize cathode zakuthupi otetezeka mphamvu yosungirako maselo, amene ali ndi moyo wautali, voliyumu mkulu ndi makhalidwe mkulu mphamvu, ndipo adzakhala azimuth azimuth zinthu electrolyte mu rechargeable mabatire lifiyamu-ion, mphira galasi, mikangano zida ndi kuwala. ndi zipangizo zamagetsi zotetezeka ndi zina. Sulfide Solid Electrolytes Lithium Sulfur Li2S ndi Li2S+GeS2+ P2S5 ndi Li2S+SiS2+ Al2S3akukulanso gawo lofunikira la dongosolo lamphamvu lamphamvu lamagetsi ndi zida zosungiramo mphamvu zankhondo, galimoto yamagetsi, sitima yapamadzi ndi ndege.
Kufotokozera zaukadaulo
Sulfida Compounds makamaka amatchula zinthu zitsulo ndi mankhwala metalloid, amene stoichiometric zikuchokera kusintha mu osiyanasiyana osiyanasiyana kupanga pawiri ofotokoza olimba njira.Inter-zitsulo pawiri ndi katundu wake kwambiri pakati zitsulo ndi ceramic, ndi kukhala nthambi yofunika ya zipangizo zatsopano structural.Sulfides Compound of Arsenic Sulfide As2S3, Bismuth Sulfide Bi2S3, Gallium Sulfide Ga2S3, Germanium Sulfide GeS2, Indium sulfide mu2S3, Lithium Sulfide Li2S, Molybdenum sulfide MoS2, Selenium Sulfidi SeS2, Sliver Sulfidi Ag2S, Solid Electrolytes Li2S+GeS2+P2S5ndi Li2S+SiS2+ Al2S3Multi-element sulfide composite electrode material, Tin Selenide SnS2, Titanium Sulfide TiS2, Zinc Sulfide ZnS ndi (Li, Na, K, Be, Mg, Ca) mankhwala ndi mankhwala a Rare Earth amathanso kupangidwa ngati ufa, granule, mtanda, bar, crystal ndi gawo lapansi.
Lithium sulfide Li2S 3N 4N (99.9%, 99.99%) ndi Solid Electrolyte Materials Li2S+GeS2+ P2S5ndi Li2S+SiS2+ Al2S399.99% 4N ku Western Minmetals (SC) Corporation ikhoza kuperekedwa mu mawonekedwe a ufa -60mesh, -80mesh, granule 1-6mm, mtanda 1-20mm, chunk, opanda kanthu, kristalo wochuluka ndi kristalo umodzi etc kapena monga mwamakonda kuti mufikire njira yabwino.Lithium sulfide Li2S250g, 500g mu botolo polyethylene, kapena 1kg-5kg mu thumba gulu, katoni bokosi kunja.
Ayi. | Kanthu | Mafotokozedwe Okhazikika | ||
Fomula | Chiyero | Kukula & Kulongedza | ||
1 | Arsenic sulfide | As2S3 | 5N | -60mesh, -80mesh ufa, 1-20mm mtanda wosakhazikika, 1-6mm granule, chandamale kapena chopanda kanthu.
500g kapena 1000g mu polyethylene botolo kapena gulu thumba, katoni bokosi kunja.
Kuphatikizika kwa mankhwala a sulfide kumapezeka pakafunsidwa. Kufotokozera kwapadera ndi kugwiritsa ntchito kungasinthidwe kuti zikhale bwino. |
2 | Bismuth sulfide | Bi2S3 | 4N | |
3 | Cadmium sulfide | CdS | 5N | |
4 | Gallium sulfide | Ga2S3 | 4n5n | |
5 | Germany sulfide | GeS2 | 4n5n | |
6 | Indium sulfide | In2S3 | 4N | |
7 | Lithium sulfide | Li2S | 3n4n | |
8 | Molybdenum sulfide | MoS2 | 4N | |
9 | Selenium sulfide | SeS2 | 4n5n | |
10 | Silver Sulfidi | Ag2S | 5N | |
11 | Tin sulfide | SnS2 | 4n5n | |
12 | Titanium sulfide | TiS2 | 3N 4N 5N | |
13 | Zinc sulfide | ZnS | 3N | |
14 | Sulfide Solid Electrolytes | Li2S+GeS2+P2S5 | 4N | |
Li2S+SiS2+ Al2S3 | 4N |
Ayi. | Kanthu | Mafotokozedwe Okhazikika | |
Chiyero | Kusayera PPM Max aliyense | ||
1 | Lithium sulfide Li2S | 3N 99.9% | Co 35, Cu 20, Al/Bi/Sb 30, Mg 50, Pb/Mn/As/Te 10, Fe/Ti/Si 80, Na 100 |
2 | Lithium sulfide Li2S | 4N 99.99% | Ag/Al/Cu/Mg/Ni/Cd/Zn/Pb/As 1.0, Ca 4.0, Fe/Si 5.0, Mn 3.0 |
3 | Phosphorous Sulfidi P2S5 | 3N 99.9% | Ag/Cu/Mg/Bi/Sb/Zn/Pb 50, Al/Co 40, Au 30, Fe 90 |
Sulfide Solid Electrolytes Li2S+GeS2+P2S5 ndi Li2S+SiS2+Al2S3 3n4n(99.9%, 99.99%) Battery ya lithiamu yolimba yokhala ndi electrolyte yosayaka imatha kupewa ngozi yoyaka komanso kuphulika, moyo waufupi komanso kuchepa kwa mphamvu zamagetsi, pomwe ma electrolyte olimba amathanso kulepheretsa mapangidwe a lithiamu dendrite kuti apititse patsogolo moyo wautumiki wa batri. .Zina mwa zomwe ma electrolyte olimba a sulfide afala kwambiri ndipo amakopa chidwi chifukwa ali ndi ma conductivity apamwamba komanso mawotchi abwino kuti apange mawonekedwe abwino pakati pa zolimba.Ma electrolyte olimba a sulfide crystalline ndi thio-LISICON, conductor wa lithiamu superionic wopezeka mu Li.2S-GeS2-P2S5dongosolo, lomwe limasonyeza apamwamba lithiamu-ion madutsidwe 2.2 × 10-3s cm-1kutentha firiji, pamodzi ndi negligible magetsi madutsidwe, mkulu electrochemical bata, lonse ntchito voteji zenera.Li2S+GeS2+ P2S5 ndi Li2S+SiS2+ Al2S3, buku ndi kulonjeza ma electrolyte olimba okonzedwa ndi njira yopangira mphamvu kwambiri ya mpira-mphero kapena njira yachizolowezi yosungunula, imakhala ngati kondakitala wa ionic ndi nembanemba yolekanitsa mu mabatire a lithiamu amtundu wokhazikika.
Malangizo Ogulira
Li2S Li2S+GeS2+ P2S5 Li2S+SiS2+ Al2S3